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Question

How many products will be aromatic ion when AgNO3 reacts with the following compounds.


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Solution

Here, 4n+2=2
n=0
Thus it is aromatic.

Here, 4n=4
n=1, hence antiaromatic.

Here, 4n+2=6
n=1
Hence it is aromatic.


Here, 4n+2=6
n=1. Lone pair is involved in delocalisation.
Hence it is aromatic.
Here, 4n+2=6
n=1
Here both the starting material and the product is aromatic.

Other three compounds will not form AgCl since they cannot form stable carbocation.

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