The correct option is C 19
Let us count 7 in 2 ways, with 7x and 7y being numbers between 11 and 100.
For 7x, x will take values from 1 to 9−9 values
For 7y, y will take values from 0 to 9−10 values
Total: 9+10 values = 19.
The digit 7 appears 19 times when you write from 11 to 100