We assess the molar quantity of water in the usual way...
Number of moles=massmolar mass
≡54⋅g18.01⋅g⋅mol−1=3.00⋅mol
But the mol is like the dozen or the gross, it specifies a NUMBER, here NA≡6.022×1023⋅mol. Why do we use such an absurdly large number? Because NA⋅1H⋅atoms have a MASS of 1⋅g precisely...and thusthe mole is the link between the micro-world of atoms, and molecules, to the macro world of grams and litres....
And so (finally!) we take the product...
Number of water molecules=molar quantity×Avogadro's number.
=3.00⋅mol×6.022×1023⋅mol−1a number as required..=??⋅water molecules