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Question

How much amount of CaCO3 in grams having percentage purity 50 percent produces 0.56 L of CO2 at STP on heating?

A
2.5 g
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B
7 g
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C
5 g
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D
3.5 g
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Solution

The correct option is C 5 g
We know one mole of any substance at STP has a volume of 22.4 L. So 0.56 L of CO2 means 140moles of CO2
CaCO3CaO+CO2
By stoichiometry
1 mole CaCO31 mole CO2
140mole of CaCO3140moles of CO2
Molar mass of CaCO3=100 g
So, mass of pure CaCO3 required =140×100=2.5 g
But here since purity of CaCO3 is 50 percent, amount of CaCO3 required =2.5 g×2=5 g

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