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Question

How much amount of CuSO4.5H2O required for liberation of 2.54 g I2 when titrated with KI?

A
2.5 gm
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B
4.99 gm
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C
2.4 gm
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D
1.2 gm
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Solution

The correct option is B 4.99 gm
2CuSO4+4KICu2I2+2K2SO4+I2

Molecular wt of CuSO4.5H2O = 249.6 g/mol

Molecular wt of I2 = 253.8 g/mol

2 moles (500 g) of CuSO4.5H2O is required to liberate 1 mol (254 g) of I2

Amount of CuSO4.5H2O required for 2.54 g of I2 is

=2.54×500254=5

5g CuSO4.5H2O

Therefore, option B is correct.

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