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Question

How much copper is deposited on the cathode if a current of 3A is passed through aqueous CuSO4 solution for 15 minutes?

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Solution

3 amperes is 5 coulombs per second, 3 C/s

So the total charge in 30 minutes is Q=3C/s×15min×60s/min=2700C

Then the number of moles of copper plated out (n) is:

n=QzF
where z is the number of electrons in the half-cell reaction (in this case, 2)
and F is the Faraday constant = 96,485/mol

So, n=2700(2×96485)=0.0139mol

And this is 63.546×0.0139=4.54g

So 4.54 grams are plated deposited at the cathode.

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