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Standard X
Chemistry
Electrolysis and Electrolytes
How much curr...
Question
How much current is required to obtain half mole
N
i
from electrolysis of
N
i
S
O
4
solution?
A
2
F
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B
1
F
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C
0.5
F
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D
4
F
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Solution
The correct option is
D
1
F
By Faraday's law,
w
=
Z
q
.
w
=
E
96500
×
q
[
q
in coulomb]
Where
E
=
equivalent weight
=
M
2
in this case.
∴
w
M
=
1
2
×
Q
[where
Q
is in farads].
∵
w
M
=
1
2
⟹
Q
=
1
F
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0
Similar questions
Q.
For how much time,
10
ampere electric current should be passed through a dilute aqueous
N
i
S
O
4
solution during electrolysis using inert electrode, in order to get
5.85
g
of Nickel?
[At. weight of
N
i
=
58.5
g
m
]
Q.
What weight of Ni is plated out in an electrolysis of aqueous
N
i
S
O
4
solution that it takes place to deposit 2g of Ag in a silver coulometer that is arranged in series with
N
i
S
O
4
electrolytic cell.[atomic weight of Ag=107.8 amu,atomic weight of Ni=58.7 amu]
Q.
Electrolysis of dilute aqueous
N
a
C
l
solution was carried out by passing
10
mA
current. The time required ( in seconds) to liberate 0.01 mole of
H
2
gas at the cathode is
x
×
10
4
s
. Find the value of
x
.
(
1
F
=
96500
C mol
−
1
)
.
Q.
A current of
965
A is passed for
1
s
through
1
L
solution of
0.02
N
N
i
S
O
4
using Ni electrodes. What is the new concentration of
N
i
S
O
4
?
Q.
(a) State Faraday's first law of electrolysis. How much charge in terms of faraday is required for the reduction of
1
mole of
C
u
2
+
to
C
u
?
(b) Calculate emf of the following cell at
298
K
:
M
g
(
s
)
|
M
g
2
+
(
0.1
M
)
|
|
C
u
2
+
(
0.01
M
)
|
C
u
(
s
)
[Given
E
0
c
e
l
l
=
+
2.71
V
,
1
F
=
96500
C
m
o
l
−
1
]
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