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Question

How much electricity in terms of Faraday is required to produce:

(i) 20 g of Ca from molten CaCl2
(ii) 40 g of Al from molten Al2O3
[Given : Molar mass of calcium & Aluminium are 40 g mol1 & 27 g mol1 respectively]

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Solution

(1) Ca2++2eCa

1 mole (40 g) of Ca will require 2 F of electricity.
20 g (0.5 mole) of Ca will require 1 F of electricity.

(2) Al3++3eAl

1 mole (27 g) of Al will require 3 moles of electrons.
40 g of Al will require 3×40F27=4.4 F

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