Give reasons for the following: (i) In the contact process, sulphur trioxide formed is dissolved in 98% sulphuric acid and not in water. (ii) When solution of sulphur dioxide is exposed to air, it gets converted to sulphuric acid. (iii) When diluting concentrated sulphuric acid, the acid should be added to water and not water to the acid. (iv) When concentrated sulphuric acid is exposed to air, its volume increases and it becomes slightly dilute. (v) Sulphuric acid can form two kinds of salts with sodium chloride. (vi) When barium chloride is added to dilute sulphuric acid, a white precipitate is formed. (vii) When carbon is heated with concentrated sulphuric acid, carbon dioxide is formed. (viii) Ammonia gas cannot be dried by passing through concentrated sulphuric acid. (ix) When concentrated sulphuric acid is added to sugar/glucose, a black mass is left behind. (x) Concentrated sulphuric acid should not be added to oxalic acid or formic acid in the open laboratory. (xi) When concentrated sulphuric acid is added to blue crystalline copper sulphate, it turns powdery white. (xii) Concentrated sulphuric acid must be stored in airtight bottles. (xiii) Cotton clothes get burnt with concentrated sulphuric acid. (xiv) H2SO4 cannot be prepared by heating sodium sulphate with conc. HCl or HNO3.
Which gas is produced when a mixture of iron filling and sulphur powder is treated with dilute sulphuric acid at room temperature? Which gas would be produced if the same mixture is heated strongly cooled and then treated with dilute sulphuric acid? What is the cause of difference in this property