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Question

How much heat energy should be added to the gaseous mixture consisting of 1 g of hydrogen and 1 g of helium to raise its temperature from 0oC to 100oC at constant volume? ( in cal )

A
325
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B
300
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C
225
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D
250
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Solution

The correct option is A 325
Hydrogen is diatomic. Hence its Cv=Cv1=2.5R
Helium is monoatomic.Hence its Cv=Cv2=1.5R
Thus heat required, ΔQ=(n1Cv1+n2Cv2)× ΔT
Here, n1=number of moles of hydrogen=0.5, n2=number of moles of helium=0.25, ΔT =change in temperature=100K
Hence,
ΔQ=325 cal

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