Let the volume of the pure alcohol be x ml.
Initial concentration=15%
So, initial amount of alcohol in the solution will be=15100×400=60 ml.
To make the strength of the solution 32%,
we will keep the amount of water constant and add x volume of pure alcohol.
On adding pure alcohol, the volume of the solution increases to 400 + according to the question, we have:x+60400+x=32100
100x+6000)=12800+32x
⇒100x−32x=12800−6000
⇒68x=6800
∴x=100
So, amount of pure alcohol to be added=100 ml