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Question

How to write chemical formulas of compounds which has more than two components

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Solution

An ion is an atom with an electric charge (positive or negative).

A polyatomic ion is a group of atoms with an electric charge. (Even though it is a group of atoms it acts like it were a single atom.)

The names of nearly all polyatomic ions end with the letters –ate or –ite. Beware three exceptions: cyanide, hydroxide, and peroxide. These ions end with “ide” which can trick into thinking you have a binary compound when you actually have a ternary compound.

Naming ternary compounds

Follow the naming systems for Type I and Type II binary compounds but…

DON’T CHANGE THE NAME OF THE POLYATOMIC ION.

Examples

Na2SO4 à sodium sulfate

KH2PO4 à potassium dihydrogen phosphate

Fe(NO3)3 à iron (III) nitrate

Mn(OH)2 à manganese (II) hydroxide

Na2SO3 à sodium sulfite

Calcium hydroxide à Ca(OH)2

Sodium phosphate à Na3PO4

Ammonium dichromate à (NH4)2Cr2O7

Cobalt (II) perchlorate à Co(ClO4)2

Copper (II) nitrite à Cu(NO2)2

Naming Polyatomic Ions that Contain Oxygen

There are many atoms that form several different polyatomic ions with oxygen. The naming system for these ions is based on two things: the most common ion in each series and the number of oxygen atoms compared to the most common ion. The ones that concern us most are ions of phosphorus, sulfur, nitrogen, chlorine, and carbon. Memorize these ions!

PO43- = phosphate

SO42- = sulfate

NO3- = nitrate

ClO3- = chlorate

CO32- = carbonate

Naming Polyatomic Ions that Contain Oxygen

One more oxygen that the most common............... per___ate

Most common..................................................... ___ate

One less oxygen that the most common.................. ___ite

Two less oxygens than the most common............... hypo___ite

Examples

PO53- = perphosphate

PO43- = phosphate (most common)

PO33- = phosphite

PO23- = hypophosphite

SO52- = persulfate

SO42- = sulfate (most common)

SO32- = sulfite

SO22- = hyposulfite


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