James Chadwick, a scientist, conducted an experiment in which he hit Beryllium with alpha particles produced by Polonium's natural radioactive disintegration in 1932.
The radiation that resulted had a high penetration through a lead shield, which could not be explained by the particles available at the time.
The following chemical reaction was observed:
To prove that the discovered particle was a neutron, he measured mass of the particle using the velocity of the expelled protons and came to the conclusion that the mass of neutrons was 1.0067 times mass of a proton.