Ethane and ethene can be differentiated by the bromine test. The colour of bromine water is red-brown.
Unsaturated hydrocarbons decolourised the bromine water, whereas saturated hydrocarbon will not decolourise it.
Ethene is an unsaturated compound and ethane is a saturated compound. Ethene will react with bromine water and will decolourise bromine water but ethane will not. The reaction is :
CH2=CH2+Br2⟶CH2Br−CH2Br
CH3−CH3+Br2⟶Noreaction