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Question

How will you distinguish primary, secondary and tertiary alcohol by Lucas Test?

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Solution

Lucas Test is used to distinguish primary, secondary and tertiary alcohols by using the Lucas reagent (anhy ZnCl2+HCl).
CH3CH3OH1alcohol+HClanhy ZnCl2−−−−−−CH3CH3Cl+H2OTurbidity appears on heating

CH3OH|CHCH32alcohol+HClanhy. ZnCl2−−−−−−CH3CH|CH3Cl+H2OTurbidity appears within 5 min

CH3CH3|C|CH3OH3alcohol+HClanhy. ZnCl2−−−−−−CH3CH3|C|CH3Cl+H2OTurbidity appears immediately

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