Dear Student,
Ferrous sulphate heptahydrate on heating first looses water of crystallization to form anhydrous ferrous sulphate and then decomposes to form ferric oxide with the evolution of sulphur dioxide and sulphur trioxide.
The sulphur trioxide (SO3) and sulphur dioxide (SO2) on dissolution in water forms Sulphuric acid (H2SO4) and sulphurous acid (H2SO3) respectively hence proving that acidic oxide is present during decomposition of ferrous sulphate
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