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Geometrical Isomerism in Square Planar Geometry

Hybridization...

Question

Hybridization scheme of [Fe(H²O)5(NO+)]+² Which ligand will enter inner d orbital

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Q. Based on VBT,

[F e C l_{6}]^{3 -}

C l^{-}

as weak ligands.

F e

s p^{3} d^{2}

hybridized (outer orbital complex) having five unpaired electrons.

[F e (C N)_{6}]^{3 -}

C N^{-}

as strong ligand.

F e

d^{2} s p^{3}

hybridized (inner orbital complex) having only one unpaired electron. Hence,

[F e C l_{6}]^{3 -}

is more paramagnetic than

[F e (C N)_{8}]^{3 -}

.
If true enter 1, else enter 0.

Q. Which of the following species does not involve inner orbital hybridization?

Q. Differentiating electron in inner transition elements enters the ________ orbital.(s/p/d/f)

Q. In octahedral ligand field which of the metal's d-orbitals will feel higher repulsion?

N i (C O)_{4}

complex has no unpaired electrons. Reason: 4s-electrons of Ni atom enter into the inner d-orbitals to facilitate the

d s p^{2}

-hybridization in Ni atom.

Read the above assertion and reason and choose the correct option regarding it.

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