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Question

Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to a gaseous hydrocarbon containing less than four carbon atoms. (A) is _______.

A
CH3CH3
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B
CHCH
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C
CH4
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D
CH2=CH2
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Solution

The correct option is C CH4
Hydrocarbon (A) is methane (CH4). It reacts with bromine by substitution to form methyl bromide CH3Br
CH4+Br2CH3Br+HBr

Methyl bromide by Wurtz reaction is converted to a gaseous hydrocarbon containing less than four carbon atoms.
2CH3Br+2NaCH3CH3+2NaBr

In Wurtz reaction, when same alkyl halide is used, the product alkane has even number of C atoms.
The hydrocarbon containing less than four carbon atoms with even number of C atoms is ethane (CH3CH3).

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