Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to a gaseous hydrocarbon containing less than four carbon atoms. (A) is _______.
A
CH3−CH3
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B
CH≡CH
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C
CH4
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D
CH2=CH2
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Solution
The correct option is CCH4 Hydrocarbon (A) is methane (CH4). It reacts with bromine by substitution to form methyl bromide CH3−Br CH4+Br2→CH3−Br+HBr
Methyl bromide by Wurtz reaction is converted to a gaseous hydrocarbon containing less than four carbon atoms. 2CH3Br+2Na→CH3−CH3+2NaBr
In Wurtz reaction, when same alkyl halide is used, the product alkane has even number of C atoms. The hydrocarbon containing less than four carbon atoms with even number of C atoms is ethane (CH3−CH3).