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Question

Hydrogen peroxide and water contain 5.93% and 11.2% of hydrogen respectively. The data illustrates the law of:

A
constant proportions
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B
multiple proportions
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C
reciprocal proportions
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D
conservation of mass
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Solution

The correct option is B multiple proportions
For hydrogen peroxide, 100 g of sample will contain 5.93 g hydrogen and 1005.93=94.07 g oxygen respectively.
The ratio of the mass of oxygen to the mass of hydrogen in hydrogen peroxide is 94.075.93=15.86
For water, 100 g of sample will contain 11.2 g hydrogen and 10011.2=88.8 g oxygen respectively.
The ratio of the mass of oxygen to the mass of hydrogen in hydrogen peroxide is 88.811.2=7.93
The two ratios are in the proportion 15.867.93=2:1
Hence, this illustrates the Law of multiple proportions. According to this law, if two elements chemically combine with each other forming two or more compounds with different compositions by mass then the ratios of masses of two interacting elements in the two compounds are small whole numbers.

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