Question 13
Hydrogen peroxide is obtained by the electrolysis of .......
(a) water (b) sulphuric acid
(c) hydrochloric acid (d) fused sodium peroxide
(b)
Peroxodisulphate, obtained by electrolytic oxidation of acidified sulphate solutions at high current density , on hydrolysis yield hydrogen peroxide.
2HSO−4(aq)Electrolysis−−−−−−−→HO3SOOSO3H(aq)Hydrolysis−−−−−−→2HSO−4(aq)+2H+(aq)+H2O2(aq)