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Question

Hydrolysis of CH3CH2CN will synthesize:

A
Ethanoic acid
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B
Methanoic acid
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C
Propanoic acid
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D
Acetaldehyde
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Solution

The correct option is C Propanoic acid
Converting the nitrile into a carboxylic acid
There are two ways of doing this, both of which involve reacting the carbon-nitrogen triple bond with water. This is described as hydrolysis.
Acid hydrolysis:
The nitrile is heated under reflux with a dilute acid such as dilute hydrochloric acid. A carboxylic acid is formed. For example, starting from ethanenitrile you would get ethanoic acid.
Base hydrolysis:
The nitrile is heated under reflux with an alkali such as sodium hydroxide solution.
Propanenitrile (CH3CH2CN) on hydrolysis give propanoic acid.

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