Hydrolysis of the adduct formed form the reaction of ________ with methyl magnesium bromide gives 2-Methylpropan-2-ol.
A
Methanal
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B
Ethanal
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C
Propanal
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D
Propanone
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Solution
The correct option is D Propanone Grignard reagent react with formaldehyde to form 1∘ alcohol.
Grignard reagent react with aldehyde except formaldehyde to form 2∘ alcohol.
Grignard reagent react with ketone to form 3∘ alcohol.
2-Methylpropan-2-ol is a tertiary alcohol which is produced from the hydrolysis of the adduct formed between a ketone and a Grignard reagent. Hence option (d) is correct.