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Stereoisomerism

I. CH3CH2NH...

Question

I. $C H_{3} C H_{2} N H C H_{3}$
II. $C H_{3} C H_{2} C H_{3} | C H N H C H_{3}$
III. (ref. image)
IV. (ref. image)
Which of the following amines can be resolved into enantiomers?

I, II

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III, IV

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I, III

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II, IV

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Solution

The correct option is D II, IV
II has $α$ -carbon chiral while in IV, N is stereocentre. So they can form diastereomers salt on treatment with racemic acids and hence can be separated.

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