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How to Draw Mechanisms

(I) Draw the ...

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(I) Draw the resonating structure of $C_{6} H_{5} {N O}_{2}$ and $C_{6} H_{5} O H$ .
(II) Why ${({C H}_{3})}_{3} C^{+}$ carbocation is more stable than ${C H}_{3}$ ?

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Q. Arrange the following in decreasing order of their acidic character:
(i)

{C H}_{3} - O - C_{6} H_{4} O H

C_{6} H_{5} - O H

{N O}_{2} - C_{6} H_{4} O H

Q. Why cyclopropanyl carbocation is more stable than benzyl carbocation but less stable than tropylium carbocation? It is true that the more will be the resonating structure of carbocation ,more will be the stability of the carbocation, then why benzyl carbocation with 5 resonating structure is less stable than cyclopropanyl carbocation having 3 resonating structure. explain this.

Q. The boiling points of

C_{6} H_{6}, {C H}_{3} O H, C_{6} H_{5} {N H}_{2}

C_{6} H_{5} {N O}_{2}

80^{0} C, 65^{0} C, 184^{0} C

212^{0} C

respectively. Which of these will show highest vapour pressure at room temperature?

{(C H_{3})}_{3} C^{\oplus}

is more stable than

C H_{3} \oplus C H_{2}

\oplus C H_{3}

is less stable.

Q. Most stable carbocation formed from

{(C H_{3})}_{3} C - B r, {(C_{6} H_{5})}_{3} C B r, {(C_{6} H_{5})}_{2} C H B r

C_{6} H_{5} C H_{2} B r

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