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Question

i) Fe(CN)x6+H2O2+H+ Fe(CN)y6+H2O
(ii) [Fe(CN6)]p+H2O2+OH[Fe(CN6)]q+O2+H2O
Which of the following is true?

A
x and y are 4 and 3 respectively
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B
p and q are 4 and 3 respectively
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C
In (i), H2O2 acts as a oxidising agent
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D
In (ii), H2O2 acts as a redusing agent
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Solution

The correct options are
A x and y are 4 and 3 respectively
C In (i), H2O2 acts as a oxidising agent
D In (ii), H2O2 acts as a redusing agent
(i)[Fe+2(CN)6]4+H2O2+H+[Fe+3(CN)6]3+H2OH2O2actsasoxidisingagent,x=4,y=3.(ii)[Fe+3(CN)6]3+H2O2+OH[Fe+2(CN)6]4+O2H2O2actsasreducingagent,p=3,q=4.

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