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Question

i. Me3CO
ii. MeO
iii. MeCH2O
iv. Me2CHO
v. Refer image.
The decreasing order of SN2 reactivity of alkoxide nucleophiles:
253558_8fe3cc7a840546dd987a51b91d438b89.png

A
(i)>(iv)>(v)>(iii)>(ii)
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B
(ii)>(iii)>(v)>(iv)>(i)
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C
(i)>(v)>(iv)>(iii)>(ii)
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D
(ii)>(iii)>(iv)>(v)>(i)
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Solution

The correct option is D (ii)>(iii)>(iv)>(v)>(i)
The decreasing order is (ii)>(iii)>(v)>(iv)>(i)
As the number of methyl groups increases , the reactivity of alkoxide nucleophiles decreases due to increase in the steric hinderance.

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