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Byju's Answer
Standard XII
Chemistry
Types of Catalysis
I. N 2 g +2 O...
Question
I
.
N
2
(
g
)
+
2
O
2
(
g
)
⟶
2
N
O
2
(
g
)
;
Δ
H
I
=
16.18
kcal
I
I
.
N
2
(
g
)
+
2
O
2
(
g
)
⟶
N
2
O
4
(
g
)
;
Δ
H
I
I
=
2.31
kcal
Based on the above reactions:
A
N
O
2
is more stable than
N
2
O
4
at low temperature
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B
N
2
O
4
is more stable than
N
O
2
at low temperature
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C
Both are equally stable at low temperature
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D
None of the above
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Solution
The correct option is
B
N
2
O
4
is more stable than
N
O
2
at low temperature
From the given reactions, substracting I from II,
2
N
O
2
⟶
N
2
O
4
=
2.31
−
16.78
=
−
13.87
kcal
The reaction is exothermic, so the product is more stable.
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Similar questions
Q.
Given the following reactions with their enthalpy changes, at
25
∘
C
,
N
2
(
g
)
+
2
O
2
(
g
)
→
2
N
O
2
(
g
)
;
△
H
=
16.18
k
c
a
l
N
2
(
g
)
+
2
O
2
(
g
)
→
N
2
O
4
(
g
)
;
△
H
=
2.31
k
c
a
l
Calculate the enthalpy of dimerisation of
N
O
2
. Is
N
2
O
4
apt to be stable with respect to
N
O
2
at
25
∘
C
?
(
13.87
k
c
a
l
,
N
2
O
4
stable only at low temp.)
Q.
Given the following reactions
I :
N
2
(
g
)
+
2
O
2
(
g
)
→
2
N
O
4
(
g
)
,
Δ
H
I
=
16.18
k
c
a
l
II :
N
2
(
g
)
+
2
O
2
(
g
)
→
N
2
O
4
(
g
)
,
Δ
H
I
I
=
2.31
k
c
a
l
Which amongs
N
O
2
(
g
)
and
N
2
O
4
(
g
)
is more stable?
Q.
Assertion:
N
O
2
and
C
O
2
both odd electron molecules and hence dimerizes.
Reason :- On dimerisation,
N
O
2
is converted to stable
N
2
O
4
molecule with even number of electrons.
Q.
For the reaction
N
2
(
g
)
+
3
H
2
(
g
)
⇌
2
N
H
3
(
g
)
,
Δ
H
=
−
v
e
. The formation of
N
H
3
(
g
)
is favored a
Q.
N
2
O
4
(
g
)
⇌
2
N
O
2
(
g
)
In this reaction the dissociation of
N
2
O
4
is
x
then the how much mole will of
N
2
O
4
and
N
O
2
at equilibrium.
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