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Nitration of Benzene

i What is the...

Question

(i) What is the major mononitration product of $P h - C O O - P h$ when it is reacted in a nitrating mixture?
(ii) Which of the following are formed when $P h - C O O H$ reacts with $C H_{3} M g I$ ?

A

(i)

P h - C O O - P h - N O_{2}

- ortho product
(ii) Phenol

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B

(i)

P h - C O O - P h - N O_{2}

- para product
(ii) Benzene

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C

(i)

P h - C O O - P h - N O_{2}

- para product
(ii)

P h - C H_{3}

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D

(i)

P h - C O O - P h - N O_{2}

- ortho product
(ii) Methane

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Solution

The correct option is D (i) $P h - C O O - P h - N O_{2}$ - ortho product
(ii) Methane
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Similar questions

P h - O - C H_{2} - P h + H I \to

Which of the following is formed in the above reaction?

What will be the major product when Ph – Ph is mononitrated?

Q. Degree of dissociation of

C H_{3} C O O H

N H_{4} O H

are the same. If

0.01

C H_{3} C O O H

p H = 4.0

p H

0.01

N H_{4} O H

Q. Observe the given figures and choose the correct option :

(1) pH of I is greater than pH of II and III
(2) pH of III is greater than pH of I and II
(3) pH of I, II and III is equal
(4) pH of II is greater than pH of I and III

	Column I		Column II
A	$C H_{3} - C H B r - C D_{3}$ /on treatement with alc.KOH gives $C H_{2} = C H - C D_{3}$ as a major product	P	E1 reaction
B	$P h - C H B r - C H_{3}$ reacts faster than $P h - C H B r - C D_{3}$	Q	E2 reaction
C	$P h - C H_{2} - C H_{2} - F$ on treatement with $C_{2} H_{5} O D / C_{2} H_{5} O^{-}$ gives $P h - C D = C H_{2}$ as the major product	R	E1cB reaction
D	$P h - C H_{2} - C H_{2} - B r$ and $P h - C D_{2} - C H_{2} - B r$ react with same rate	S	First order reaction

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Nitration of Benzene

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