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Question

(i) With the help of equations, give an outline for the manufacture of sulphuric acid by the contact process.
(ii) What property of sulphuric acid is shown by the reaction of concentrated sulphuric acid when heated with
(A) potassium nitrate (B) carbon? [5 MARKS]

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Solution

Each option: 2.5 MArks

(i) S+O2SO2
2SO2+O2V2O5/Pt−−−−−−400450C2SO3
SO3+H2SO4H2S2O7
H2S2O7+H2O2H2SO4

(ii) When heated with potassium nitrate conc. sulphuric acid shows its non-volatile nature.
KNO3+H2SO4(conc.)below 200C−−−−−−KHSO4+HNO3
With carbon - oxiding nature
C+2H2SO4(conc.)heatCO2+2H2O+2SO2

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