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Nomenclature of Coordination Compounds

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Question

(i) Write down the IUPAC name of the following complex:
$[C r (N H_{3})_{2} C l_{2} (e n)] C l$ (en=ethylenediamine)

(ii) Write the formula for the following complex:
Pentaamminentrito-o-cobalt (III)

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Solution

(i) Diamminedichloride ethlenediamine chromium chloride
(ii) ${[C o (N H_{3})_{5} (O N O)]}_{3}^{2 +}$

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Q. (i) Write down the IUPAC name of the following complex:

{[C o (N H_{3})_{5} C l]}_{3}^{2 +}

(ii) Write the formula for the following complex:
Potassium tetrachloridonickelate (II).

Q. Write the IUPAC names of the following coordination compounds:
(i)

[C r (N H_{3})_{3} C l_{3}]

K_{3} [F e (C N)_{6}]

[C o B r_{2} (e n)_{2}]^{+}

, (en = ethylenediamine)

Q. The correct name for the complex ion

[C o C l (O N O) (e n)_{2}]^{+}

Q. Using IUPAC norms, write the formulae for the following:
(i) Potassium trioxalatoaluminate (III)
(ii) Dichloridobis (ethane-1,2-diamine) cobalt (III).

Q. Using IUPAC norms write the formulas for the following:

(i) Tetrahydroxidozincate(II)
(ii) Potassium tetrachloridopalladate(II)

(iii) Diamminedichloridoplatinum(II)

(iv) Potassium tetracyanidonickelate(II)
(v) Pentaamminenitrito-O-cobalt(III)
(vi) Hexaamminecobalt(III) sulphate
(vii) Potassium tri(oxalato)chromate(III)
(viii) Hexaammineplatinum(IV)
(ix) Tetrabromidocuprate(II)
(x) Pentaamminenitrito-N-cobalt(III)

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