Ice and liquid water are in equilibrium at 0oC and 1 atm as shown given. Ice will be melted when:
A
piston is moved upward at constant temperature
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B
more inert He gas is added without moving the piston at a constant temperature
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C
temperature is decreased
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D
none of these
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Solution
The correct option is B more inert He gas is added without moving the piston at a constant temperature H2O(s)⇌H2O(l)
Ice and liquid water are in equilibrium at 0oC and 1atm. Applying pressures greater than 1atm ice will melt due to lowering of melting point of ice by increasing pressure.
(A) If piston is moved upward, pressure will decrease, this will not help melting of ice.
(B) If more inert He gas is added without moving the piston at constant temperature, then pressure will increase. This will help to melt the ice.
(C) If temperature is decreased, this will not help.