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Question

Ice at 20C is filled upto height h=10 cm in a uniform cylindrical vessel. Water at temperature θC is filled in another identical vessel up to the same height h=10 cm. Now, water from second vessel is poured into first vessel and it is found that level of upper surface falls through Δh=0.5 cm when thermal equilibrium is reached. Neglecting thermal capacity of vessels, change in density of water due to change in temperature and loss of heat due to radiation, calculate initial temperature θ of water in oC.
Given,

Density of water, ρw=1gcm3

Density of ice, ρi=0.9gcm3

Specific heat of water, sw=1cal/gC

Specific heat of ice, si=0.5cal/gC

Specific latent heat of ice, L=80cal/g

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Solution

Total initial mass is (0.9)(10A)+(1)(10A) where A is cross section area of cylinder. Now, let the height of ice in final situation be x. Then the height of water will be 19.5x.
By conservation of mass,

(xA)(0.9)+(A(19.5x))(1)=(0.9)(10A)+(1)(10A)

Solving this, we get x=5cm
Now, heat lost by water in cooling from θ to 0oC is consumed in heating of ice from 20oC to 0oC and conversion of 5cm of ice into water at 0oC.

Hence, (10A)(1)(θ0)=(0.9)(10A)(0.5)(0(20))+(5A)(0.9)(80)

(4.5)(100)=(10)(θ)

Ans, θ=45oC

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