Ice-water mass ratio is maintained as 1 : 1 in a given system containing water in equilibrium with ice at constant pressure. If CP(ice)=CP(water)=4.18Jg−1K−1 then molar heat capacity of such a system is
A
Zero
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B
Infinity
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C
4.182JK−1mol−1
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D
75.48JK−1mol−1
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Solution
The correct option is B Infinity The molar heat capacity is the amount of heat required to increase the temperature of one mole of a substance by one degree.If some finite heat is supplied, the ice would melt to water, without any change in temperature. So the molar heat capacity = Heatsupplied0 = Infinity.