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Standard XII
Chemistry
Oxidation of Alcohols
Identify A,B ...
Question
Identify A,B and C in the following reactions and give there structure
C
H
3
C
H
2
O
H
o
x
i
d
a
t
i
o
n
−
−−−−−−−−−−
→
K
2
C
r
2
O
7
/
H
2
S
O
4
A
C
a
C
O
3
⟶
B
d
r
y
d
i
s
t
i
l
⟶
C
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Solution
C
H
3
C
H
2
O
H
K
2
C
r
2
O
7
−
−−−−
→
H
2
S
O
4
C
H
3
C
O
O
H
(
A
)
C
a
C
O
3
−
−−−
→
C
a
(
C
H
3
C
O
O
)
2
(
B
)
d
r
y
−
−
→
d
i
s
t
.
C
H
3
C
O
C
H
3
(
C
)
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Similar questions
Q.
Identify A,B and C in the following reactions and give there structure :
C
H
3
C
H
2
O
H
K
2
C
r
2
O
7
/
H
2
S
O
4
−
−−−−−−−−−
→
o
x
i
d
a
t
i
o
n
A
C
a
C
O
3
−
−−−
→
B
d
r
y
d
i
s
t
i
l
−
−−−−
→
C
Q.
Give the structures of
A
,
B
and
C
in the following reactions:
C
H
3
C
H
2
I
N
a
C
N
→
A
O
H
−
−
−−−−−−−−−−
→
P
a
r
t
i
a
l
h
y
d
r
o
l
y
s
i
s
B
N
a
O
H
+
B
r
2
→
C
Q.
Identify the compounds 'A', 'B' and 'C' in the following reaction and rewrite the complete equation.
(i)
C
H
3
−
C
H
2
−
C
H
2
−
C
H
O
¯
¯¯
¯
O
H
−
−
→
A
−
H
2
O
−
−−−
→
B
H
2
/
R
a
n
e
y
N
i
−
−−−−−−−
→
C
(ii)
C
6
H
5
−
C
H
O
+
C
H
3
−
C
H
2
C
O
−
C
H
3
¯
¯¯
¯
O
H
−
−
→
A
−
H
2
O
−
−−−
→
B
I
2
/
N
a
O
H
−
−−−−−
→
C
Q.
Identify product D in the following reaction sequence :
C
H
3
−
C
H
3
|
C
|
−
C
H
3
C
H
2
C
H
2
O
H
K
2
C
r
2
O
7
;
H
2
S
O
4
−
−−−−−−−−−
→
H
2
O
h
e
a
t
A
S
O
C
l
2
−
−−−
→
B
(
C
H
3
)
2
N
H
−
−−−−−−
→
(
2
m
o
l
e
)
C
1.
L
i
A
l
H
4
d
i
e
t
h
y
l
e
t
h
e
r
−
−−−−−−−−−−−−
→
2.
H
2
O
D
Q.
Write the structures of A, B and C in the following reactions:
(
i
)
C
6
H
5
−
C
O
O
−
N
H
4
+
△
−
−
→
A
B
r
2
/
K
O
H
−
−−−−−
→
B
C
H
3
C
O
C
l
/
p
y
r
i
d
i
n
e
−
−−−−−−−−−−−
→
C
(
i
i
)
C
6
H
5
N
2
+
B
F
4
−
N
a
N
O
2
/
C
u
−
−−−−−−−−−
→
△
A
S
n
/
H
C
l
−
−−−−
→
B
C
H
C
l
3
+
a
l
c
.
K
O
H
−
−−−−−−−−−−
→
C
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