The correct option is A Respiration
Respiration and photosynthesis are natural chemical changes whereas combustion of petrol and softening of hard water are man-made chemical changes.
During respiration, glucose in the cells reacts with the oxygen inhaled from the air and forms carbon dioxide and water. The reaction involved is:
C6H12O6(s)+6O2(g)→6CO2(g)+6H2O(l)
Carbon dioxide reacts with limewater (Ca(OH)2) to form calcium carbonate (CaCO3) and water. The calcium carbonate formed is responsible for milky appearance. The reaction involved is:
CO2(g)+Ca(OH)2(aq)→CaCO3(s) + H2O(l)
During photosynthesis, plants use carbon dioxide and water in presence of sunlight to form glucose and oxygen.