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Question

Identify F:

A
HF
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B
NH3
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C
HN3
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D
None ofthese
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Solution

The correct option is C HN3
A colorless water soluble crystalline solid (A) on heating gives O2 and gives a water soluble crystalline solid (B).
2KNO3(s)2KNO2(s)+O2(g)
So, A iS KNO3(crystalline solid) and B is KNO2(water soluble crystalline solid).Both A and B impart violet coloration to the Bunsen flame
When B is heated with NH4Cl, inactive gas (C) is obtained but when A is heated with NH4Cl, a gas (D)which supports combustion is formed.
NH4Cl+KNO2N2+KCl+2H2O
So the gas C is N2.
But when A is heated with NH4Cl, a gas (D) which supports combustion is formed.
NH4Cl+KNO3NH4NO3+KCl
A gas (D) which supports combustion is NH4NO3
When gas(D) is heated with soda amide, solid substance E is obtained
NH4NO3+NaNH2NaN2+2NH3+NaNO3
solid substance E is NaN2.
The solid E, when heated with diI. H2SO4, forms a monobasic acid F; F and its salts are explosive.
NaN3+H2SO4HN3+NaHSO4
A monobasic acid F is H3N
So F is H3N
Hence option C is correct.

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