Identify the alkynes A,B,(C10H18) and (C10H16) which gives the following reactions. What is (B)?
A
Dec−6−yne
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B
Hex−1−yne
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C
Dec−5−yne
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D
Non−5−yne
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Solution
The correct option is CDec−5−yne Since alkyne (B) has no reaction with Grignard reagent, it should be internal and symmetrical alkyne, as evident from the oxidative cleavage reaction with hot alkaline KMnO4. Structure of B is: Dec−5−yne