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Question

Identify the alkynes A,B,(C10H18) and (C10H16) which gives the following reactions. What is (B)?

248135_4ec493b22641412183ccc5448d4e31d8.png

A
Dec6yne
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B
Hex1yne
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C
Dec5yne
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D
Non5yne
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Solution

The correct option is C Dec5yne
Since alkyne (B) has no reaction with Grignard reagent, it should be internal and symmetrical alkyne, as evident from the oxidative cleavage reaction with hot alkaline KMnO4.
Structure of B is: Dec5yne
299783_248135_ans_b96042b438aa4cf0be89afffef22ea5b.png

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