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Question

Identify the binary mixture(s) that can be separated into the individual compounds, by differential extraction, as shown in the given scheme?
1067690_f0f522f60a384535ae909f0133c23572.png

A
C6H5OH and C6H5COOH
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B
C6H5COOH and C6H5CH2OH
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C
C6H5CH2OH and C6H5OH
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D
C6H5CH2OH and C6H5COOH
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Solution

The correct options are
B C6H5COOH and C6H5CH2OH
D C6H5CH2OH and C6H5COOH
(A) Both are soluble in NaOH, hence inseparable.
(B) Only benzoic acid (C6H5COOH) is soluble in NaOH and, while benzyl alcohol (C6H5CH2OH)
is not. Hence, separable.
(C) Although NaOH can enable separation between benzyl alcohol (C6H5CH2OH) and phenol (C6H5OH) as
only the later is soluble in NaOH. However, in NaHCO3, both are insoluble. Hence, inseparable.
(D) α -phenylacetic acid (C6H5CH2COOH)
is soluble in NaOH and NaHCO3 . While benzyl alcohol
(C6H5CH2OH) is not. Hence, separable.
Hence: The answer is both option(B) and option(D).

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