The correct option is D both a and b
A reaction in which an insoluble solid (solid precipitate) is formed is called a precipitation reaction.
For example:
Na2CO3(aq)Sodiumcarbonate+CaCl2(aq)Calciumchloride→CaCO3(s)Calciumcarbonate+2NaCl(aq)Sodiumchloride
In this reaction, calcium carbonate is obtained as a precipitate. Hence, it is a precipitation reaction.
Another example of precipitation reaction is :
Na2SO4(aq)Sodiumsulphate+BaCl2(aq)Bariumchloride→BaSO4(s)Bariumsulphate+2NaCl(aq)Sodiumchloride
In this reaction, barium sulphate is obtained as a precipitate.