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Nomenclature of Carboxylic Acids

Identify the ...

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Identify the compound which on reaction with one mole of CH3MgI in dry ether and subsequent hydrolysis can give 2-Methyl-2-propanol. Show the mechanism of the process. What will be the observation if Lucas reagent is added to 2-Methyl-2-propanol? [3]

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Which among the following compounds on reaction with methyl magnesium bromide followed by hydrolysis with water will give 2-methyl-2-propanol?

Arrange the following alcohols in the increasing order of their acidic strength

a) 2-butanol b) methyl alcohol c) 1-propanol d) 2-methyl-2-propanol

Q. Reaction of Grignard reagent,

C_{2} H_{5} M g B r

C_{8} H_{8} O

followed by hydrolysis gives compound “A” which reacts instantly with Lucas reagent to give compound B,

C_{10} H_{13} C l .

The compound B is:

Q. Lucas test is used to differentiate and categorize primary, secondary and tertiary alcohols using a solution of anhydrous zinc chloride in concentrated hydrochloric acid. This solution is commonly referred to as “Lucas Reagent”.

2-Methyl-2-butonol can be differentiated from 3-methyl-2-butanol using Lucas reagent because:

Q. Methyl cyanide on treatment with magnesium bromide followed by subsequent hydrolysis gives :

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Nomenclature of Carboxylic Acids

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