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Question

Identify the correct combination of true (T) and false (F) of the given three statements.
STATEMENT-1: Acetophenone gives aldol condensation.
STATEMENT-2: Benzaldehyde is more reactive than acetaldehyde towards nucleophilic addition.
STATEMENT-3: Benzophenone has αHydrogens.

A
TTT
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B
FFF
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C
TFF
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D
TFT
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Solution

The correct option is C TFF
Structures of the given species are as follow:

Statement 1 is true beacuse acetophenone has αhydrogens which enable it to undergo aldol condensation.

Statement 2 is false. Acetaldehyde is more reactive than benzaldehyde toward nucleophilic addition. In benzaldehyde, the phenyl group being bulkier group produce steric hinderance for upcoming nucleophile and also the polarity of CO bond is reduce by electron donting nature of phenyl ring.

Statement 3 is also false because benzophenone does not have αhydrogen.

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