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Question

Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds:
1117395_80f3323c1a88476885a9654f4aa76e7b.PNG

A
I > II > III > IV
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B
IV > III > II > I
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C
II > I > III > IV
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D
II > III > I > IV
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Solution

The correct option is C II > I > III > IV
Due to +I effect CH3 group to an activating group NO2 has a strong I & M effect Cl has a weak I effect.
Therefore toulene has a higher electron denolty than benzene, nitrobenzene & cholrobenzene.
Thus the overall reactivity order is

Ans 2>1>3>4

1405207_1117395_ans_4cb5506530a94a0f936da62684ee9923.png

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