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Question

Identify the elements X and Y using the ionisation energy values given below :

1st Ionisation Enthalpy(KJ/mol) 2nd Ionisation Enthalpy(KJ/mol)
X 495 4563
Y 731 1450

A
X=Na ; Y=Mg
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B
X=Mg ; Y=F
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C
X=F ; Y=Mg
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D
X=Mg ; Y=Na
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Solution

The correct option is A X=Na ; Y=Mg
Due to 2p6, noble gas electronic configuration, the second ionisation enthalpy of Na is very high. That's why has large difference between IE1 and IE2 of Mg+ is 2p6,3s1.
After the loss of one electron, Mg2+ will be formed with noble gas electronic configuration. That's why it has less difference between IE1 and IE2.
Thus option (a) is the correct answer.

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