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Question

Identify the functional group in Product B?
243407.PNG

A
Ketone
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B
Carboxylic acid
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C
aldehyde
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D
none
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Solution

The correct option is D Carboxylic acid
The functional group in Product B is carboxylic group COOH.

The first step is allylic bromination with N-bromosuccinimide (NBS) in which Br atom is added to allylic C atom of cyclohexene to give compound A.
In the next step, the reaction with Mg in presence of ether gives a Grignard reagent (RMgX) which then attacks a molecule of carbon dioxide. Acid hydrolysis gives carboxylic acid.

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