Identify the major products in the following reaction.
$C_{6} H_{5} C O O H + M e M g I ⟶ ? + ?$

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Solution

Since Grignard reagent is a very strong base, it will extract protons from acidic groups.

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B

C_{6} H_{5} C O O H + N a H * C O_{3} ⟶ g a s (A) 1. {C H}_{3} M g B r - ------ \to 2. H_{3} O^{+} (B) (* C = C^{14})

C_{6} H_{5} C O O H + {C H}_{3} M g I \to

N a C l

25^{o} C

N a C l

C_{6} H_{5} C O O H

25^{o} C; C_{6} H_{5} C O O H

C_{6} H_{5} N H_{2} {A c}_{2} O - ------ \to H e a t A C o n c . H N O_{3} - ---------- \to \begin{matrix} C o n c . H_{2} S O_{4} 0 - 15^{o} C \end{matrix} B (M i n o r) a q . H_{2} S O_{4} - --------- \to H e a t C (M a j o r)

(C)

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