Identify the mismatched purine-pyrimidine pair among the following options.
Thymine - Cytosine
Adenine (a purine) and Thymine (a pyrimidine) always form a pair, while Guanine (a purine) and Cytosine (a pyrimidine) form another pair. Thymine and Cytosine are both pyrimidines, and cannot pair up.