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Question

Identify the pair of alkanes which can exhibit chain isomerism and has a neo isomer respectively?

A
C3H8,C4H10
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B
C4H10,C5H12
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C
C5H12,C6H14
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D
C6H14,C7H16
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Solution

The correct options are
B C5H12,C6H14
C C4H10,C5H12
D C6H14,C7H16
Option (A) propane; C3H8 does not show isomerism, butane; C4H10 does not have a neo isomer.
Option (B) C4H10 & C5H12
Butane exists as n-butane; CH3CH2CH2CH3 and iso-butane; CH3CH(CH3)CH3
Pentane exists as neo-pentane as; C(CH3)4
Option (C) C5H12 & C6H14
Pentane exists as n-pentane; CH3CH2CH2CH2CH3, iso-pentane; CH3CH(CH3)CH2CH3 and neo-pentane; C(CH3)4
Hexane exists as neo-hexane as; (CH3)3CC2H5
Option (D) C6H14 & C7H16
Hexane exists has five structural isomers which exist in form of n-hexane; CH3CH2CH2CH2CH2CH3, iso-hexane; CH3CH(CH3)CH2CH2CH3 and neo-hexane; (CH3)3CC2H5.
Heptane exists as neo-heptane as; (CH3)3CC3H7.

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