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Question

Identify the principal product of the following reaction?


A
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B
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C
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D
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Solution

The correct option is B
Dialdehydes undergo aldol condensation on reacting with NaOH/KOH to for α,β unsaturated ketone.

The α-hydrogens of two carbonyl are identical so it will form only one enolate ion and it leads to stable 5 membered cyclisation reaction.

Thus, mechanism of intramolecular aldol condensation of the given compound is

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