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Question

Identify the product of the following reaction.
ClCH2CH2CH2Br+KCNProduct

A
ClCH2CH2CH2CN
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B
CNCH2CH2Br
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C
CNCH2CH2CH2CN
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D
CH3CH2CH2Br
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Solution

The correct option is A ClCH2CH2CH2CN
The IUPAC name of the compound ClCH2CH2CH2Br is 1-Bromo-3-chloropropane. When 1-Bromo-3-chloropropane reacts with KCN i.e potassium cyanide, the product formed is:
ClCH2CH2CH2Br+KCNClCH2CH2CH2CN+KBr

[Note: Br is better-leaving group than Cl.]

Therefore A is the correct option.

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