Identify the products (X) and (Y)in the given reaction.
A
X=Acetophenone, Y=m-Nitroacetophenone
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B
X=Toluene, Y=m-Nitroacetophenone
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C
X=Acetophenone, Y=o-and p-Dinitroacetophenone
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D
X=Benzaldehyde, Y=m-Nitroacetophenone
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Solution
The correct option is A X=Acetophenone, Y=m-Nitroacetophenone Friedel-Crafts Acylation : One H atom attached to C atom of the benzene ring gets replaced by Acyl (RCO) group.
The attacking electrophile is an acyl carbocation RCO+) made available by Acid anhydride ((RCO)2O). −COCH3 is one of the strongest deactivating group, it reduces the electron density at ortho and para position by -R effect. Hence, it is a meta-directing group.
Hence, the correct answer is option (a).